Treatise on Poisons by Sir Robert Christison

3. _Of Turbith Mineral._

The Turbith mineral, or subsulphate of the binoxide of mercury, exists in the form of a bright lemon-yellow, heavy powder. It is soluble in 2000 parts of water, and has an acrid taste. It may be known by the effects of heat. When heated in a tube, globules of mercury are sublimed, and at the same time sulphurous acid gas is disengaged, as may be ascertained by the smell. But a better method of proving the existence of sulphuric acid in it is to expose it to the action of a solution of caustic potass: The potass separates from it the brownish-yellow peroxide, and appropriates the sulphuric acid, which may be found in the solution by acidulating with nitric acid, and then adding hydrochlorate of baryta, when a heavy, snow-white precipitate of sulphate of baryta will form. The nitric acid used in this process must be quite pure, and free of sulphuric acid, which the acid of commerce often contains.